Advances in Single-Chain Nanoparticles for Catalysis

نویسندگان

  • Jon Rubio-Cervilla
  • Edurne González
  • José A. Pomposo
چکیده

Enzymes are the most efficient catalysts known working in an aqueous environment near 12 room temperature. The folding of individual polymer chains to functional single-chain nanoparticles 13 (SCNPs) offers many opportunities for the development of artificial enzyme-mimic catalysts 14 showing both high catalytic activity and specificity. In this review, we highlight recent results 15 obtained in the use of SCNPs as bioinspired, highly-efficient nanoreactors (3–30 nm) for the 16 synthesis of a variety of nanomaterials (inorganic nanoparticles, quantum dots, carbon nanodots), 17 polymers and chemical compounds, as well as nanocontainers for CO2 capture and release. 18

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Advances in Single-Chain Nanoparticles for Catalysis Applications

Enzymes are the most efficient catalysts known for working in an aqueous environment near room temperature. The folding of individual polymer chains to functional single-chain nanoparticles (SCNPs) offers many opportunities for the development of artificial enzyme-mimic catalysts showing both high catalytic activity and specificity. In this review, we highlight recent results obtained in the us...

متن کامل

Advances in click chemistry for single-chain nanoparticle construction.

Single-chain polymeric nanoparticles are artificial folded soft nano-objects of ultra-small size which have recently gained prominence in nanoscience and nanotechnology due to their exceptional and sometimes unique properties. This review focuses on the current state of the investigations of click chemistry techniques for highly-efficient single-chain nanoparticle construction. Additionally, re...

متن کامل

Advances in single chain technology.

The recent ability to manipulate and visualize single atoms at atomic level has given rise to modern bottom-up nanotechnology. Similar exquisite degree of control at the individual polymeric chain level for producing functional soft nanoentities is expected to become a reality in the next few years through the full development of so-called "single chain technology". Ultra-small unimolecular sof...

متن کامل

Spatiotemporal catalytic dynamics within single nanocatalysts revealed by single-molecule microscopy.

This review discusses the latest advances in using single-molecule microscopy of fluorogenic reactions to examine and understand the spatiotemporal catalytic behaviors of single metal nanoparticles of various shapes including pseudospheres, nanorods, and nanoplates. Real-time single-turnover kinetics reveal size-, catalysis-, and metal-dependent temporal activity fluctuations of single pseudosp...

متن کامل

SPION-A-Pd(EDTA) (superparamagnetic iron oxide nanoparticles-A-ethylendiamine tetraacetic acid) as a robust nanocatalyst for Buchwald-Hartwig C-N Coupling Reaction

During thelast20-30 years, palladium-catalyzed reactions have witnessed tremendous advances in the industrial and organic reactions such as hydrogenation, coupling, cyanation and amination. Despite the wide utility of Pd-catalysts in these reactions, they suffer from a number of drawbacks such as recovery, reuse of catalyst and remain as  a contaminant in the products at the end of the reaction...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2017